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聚醚砜树脂
聚醚砜树脂---透明琥珀色的无定型树脂,具有优异的耐热性,优良的尺寸安定
性,以及良好的耐化学品性.另外PES对急剧温度变化显现优良的可靠性,且在高温
长期使用有优良的可靠性.加工成型性优良以及优良的性质使PES有广泛的应用.
编辑本段化工原料
简介
聚醚砜树脂(PES)是英国ICI公司在1972年开发的一 种综合性能优异 PES
颗粒
的热塑性高分子材料,是目前得到应用的 为数不多的特种工程塑料之一。它具有
优良的耐热性能、 物理机械性能、绝缘性能等,特别是具有可以在高温下连 续
使用和在温度急剧变化的环境中仍能保持性能稳定等突出优点,在许多领域已经
得到广泛应用。
特性
◎耐热性 热变型温度在200~220℃,连续使用温度为180~200℃,UL温度指
数为180℃。 ◎耐水解性 可耐150~160℃热水或蒸气,在高温下也不受酸、
碱的侵蚀。 ◎模量的温度依赖性 其模量在-100℃到200℃几乎不变,特别在
100℃以上比任何一种热塑性树脂都好。 ◎抗蠕变性 在180℃以下的温度范
围内其抗蠕变性是热塑性树脂当中最优异的一种,特别是玻璃纤维增强PES树脂比
某些热固性树脂还好。 ◎尺寸稳定性 线膨胀系数小,而且其温度信赖性也
小是其特点。特点是30%玻璃纤维增强PES树脂,其线膨胀系数只有2.3×10-5 /℃
,并且直到200℃仍然可以保持与铝相近似的值。 ◎耐冲击性 具有与聚碳酸
酯相同的耐冲击性。不增强的树脂可以铆接,但对尖细的 PES制品
切口较敏感,因此设计上要注意。 ◎无毒性 在卫生标准方面,被美国FDA认
可,也符合日本厚生省第434号和178号公告的要求。 ◎难燃性 具有自熄性
,不添加任何阻燃剂即有优异的难燃性,可达UL94V-0级(0.46mm) ◎耐化
学药品性 PES耐汽油、机油、润滑油等油类和氟里昂等清洗剂,它的耐溶剂开裂
性是非晶树脂中最好的。但它耐丙酮、氯仿等极性溶剂的性能不好,使用时应加
以注意。
耐化学药品特性
表1 PES的耐化学药品特性 无机试剂 影响程度 液氨 A 氨水
A 50%氢氧化钠 A 10%氢氧化钾 A 10%硝酸 A 10%盐酸 A
浓盐酸 A 浓硫酸 C 浓硝酸 C 醋酸 A 硼酸 A 双氧水 A
硫化氢 A 碘化钾中的碘 B 有机试剂 影响程度 苯 A 安
息香酸 A 丙酸 A 草酸 A 环已烷 A 环已醇 A 环已酮 C
甲醇 A 甘油 A 三氯乙烷 C 三氯甲烷 A 二甲苯 B 石
油醚 A 乙二醇 A 注:A:无影响,20℃无吸收; B:稍有影响,有少量
吸收或溶胀, 但在 某些应用方面有充分耐用性; C:有较大影响,不能使用
PES的标准物性数据
◆ PES聚醚砜树脂 PES树脂不仅具有优异的耐热性和机械性能,其加工
性能也很好,不仅可以挤出成型、注射成型、模压成型、吹塑成型、吸塑成型和
制成发泡体,还可以进行镀膜、超声波融接、机械加工、溶剂粘接、涂敷等二次
加工。 PES的注射成型工艺 项 目 条 件 根部 290~320 料筒
温度(℃)中间 300~350 喷嘴 300~350 模具温度(℃) 140~160
注射压力(MPa)100~140 螺杆背压(MPa) 50~100 保持压(MPa) 50~
70 注射速度 中速~高速 螺杆转数(rpm) 50~60 ◆ PES聚醚砜
树脂
电器、电子领域
利用PES的可耐焊锡性、尺寸 稳定性好、耐各种清洗剂、可镶嵌金属件
、与环氧树脂粘结性好等优点,作为H级绝缘材料用于电子、电器领域。已经开发
的主要制品有线圈骨架,电位计的外壳和底座,吹发器零件,印刷线路板、按钮
式开关、可控硅的绝缘体,电动工具马达的绝缘体、打印机、送风机、继电器等
的线圈骨架、DIP开关,各类接插件等。还可以采用挤出成型法制成不同厚度的薄
膜用于各种电子设备和电器产品。
机 械 领 域
利用其高温抗蠕变性,尺寸稳定性、耐油性、韧性好等优点,在一般树脂不
能满足使用要求的地方得到了广泛应用。已经开发的主要制品有各种机器的杠杆
、柄、支架等,X-射线装置的观察玻璃,链锯、农机发动机和汽化器等的绝缘体
,活塞环,耐热滚珠,齿轮,复印机零件,照相机零件,放映机零部件,工业用
吹风机罩,汽车空调的零部件,电弧焊枪的手柄,各种分析仪器元件等。
汽 车 领 域
主要利用其在-100℃~190℃广阔温度范围内的刚性和尺寸稳定性,高温抗蠕
变性,耐汽油、柴油、各类机油等特长。已经开发的制品有各种轴承保持架,制
动轴的轴瓦,点火器的噪音消除器,发动机齿轮,汽化器的线圈骨架,雾灯的反
射镜,止推环等。
热 水 领 域
主要利用其在160℃的热水或蒸气中还能保持优异的抗蠕变性, 刚性和尺寸
稳定性等特点。开发的主要制品有热水、蒸气用阀门,防腐蚀电极的绝缘体,温
度传感器的元件,各种液体和粉体泵的泵体和叶轮,散热器阀门,超滤装置用零
部件等。 医疗器具、食品加工机械领域 主要利用其可以采用蒸气灭菌
、干蒸(180℃)灭菌、V射线灭菌等灭菌法消毒,而且可以耐反复消毒等特点。
开发的主要制品有接触透镜灭菌器,牙科用钻的柄,外科用容器,注射器,食品
工业用阀门和管子。
其 它 领 域
涂 料 由于它有与铁、铅等金属的附着力好,涂层表面硬度高等优点,
PES聚醚砜与聚四氟乙烯可配制成耐腐蚀、防辐射、绝缘性能好,阻燃、无毒、与
金属附着力最佳的不粘涂料、低摩擦的特点。广泛应用于厨房用具、家用电器、
轻工五金、工业模具、塑胶机械等行业。 另外,PES可加工成超细粉,用于
粉末喷涂和液体涂料。
CoorsTek Neat PES CoorsTek PES
CoorsTek PES 20GB CoorsTek PES
Edgetek™ ES-30GF/000 Black 普立万公司 PES
Generic PESU - Carbon Fiber Reinforcement Generic PES
Generic PESU - Glass Fiber Reinforcement Generic PES
Generic PESU Generic PES
HiFill® PES GF10 TP Composites, Inc. PES
HiFill® PES GF20 TL15 LE TP Composites, Inc. PES
HiFill® PES GF20 TP Composites, Inc. PES
HiFill® PES GF30 TP Composites, Inc. PES
HiFill® PES GF40 TP Composites, Inc. PES
HiFill® PES GM20 WT139 TP Composites, Inc. PES
Hiprolon® 11 PES Suzhou Hipro Polymers Co., Ltd. 尼龙,未指定
Hiprolon® 211 PES Suzhou Hipro Polymers Co., Ltd. 尼龙,未指定
INELEC PESCF10 Infinity Compounding Corp. PES
INELEC PESCF20 Infinity Compounding Corp. PES
INELEC PESCF30 Infinity Compounding Corp. PES
INLUBE PESCF10TF10 Infinity Compounding Corp. PES
INLUBE PESCF20TF10 Infinity Compounding Corp. PES
INLUBE PESCF30TF15 Infinity Compounding Corp. PES
INLUBE PESGF20TF15 Infinity Compounding Corp. PES
INSTRUC PESGF10 Infinity Compounding Corp. PES
INSTRUC PESGF20 Infinity Compounding Corp. PES
INSTRUC PESGF30 Infinity Compounding Corp. PES
Kern PES GF20 Kern GmbH PES
Kern PES GF30 Kern GmbH PES
Kern PES Kern GmbH PES
Lapex A G/10 LATI S.p.A. PES
Lapex A G/20 LATI S.p.A. PES
Lapex A G/30 LATI S.p.A. PES
Lapex A LATI S.p.A. PES
Latilub® 85-10T G/30 LATI S.p.A. PES
LatioHM 85-06 PD01 G/15 LATI S.p.A. PES
Latishield 85-08A G/20 LATI S.p.A. PES
LEIS PES CF 20 LEIS Polytechnik - polymere Werkstoffe GmbH PES
LEIS PES GF 20 LEIS Polytechnik - polymere Werkstoffe GmbH PES
LEIS PES GF 30 LEIS Polytechnik - polymere Werkstoffe GmbH PES
LEIS PES LEIS Polytechnik - polymere Werkstoffe GmbH PES
LNP* Colorcomp* J1000 SABIC Innovative Plastics Europe PES
LNP* Colorcomp* J1000AE SABIC Innovative Plastics PES
LNP* Colorcomp* J1000E SABIC Innovative Plastics Europe PES
LNP* Colorcomp* J1000R SABIC Innovative Plastics Europe PES
LNP* Colorcomp* J1000Z SABIC Innovative Plastics Europe PES
LNP* Colorcomp* JX91550 SABIC Innovative Plastics PES
LNP* Colorcomp* JX91550 SABIC Innovative Plastics Asia Pacific PES
LNP* Lubricomp* JCL36 SABIC Innovative Plastics Europe PES
LNP* Lubricomp* JCL36E SABIC Innovative Plastics PES
LNP* Lubricomp* JFL24 SABIC Innovative Plastics Europe PES
LNP* Lubricomp* JFL34 SABIC Innovative Plastics PES
LNP* Lubricomp* JFL36 SABIC Innovative Plastics PES
LNP* Lubricomp* JFL36 SABIC Innovative Plastics Asia Pacific PES
LNP* Lubricomp* JFL36 SABIC Innovative Plastics Europe PES
LNP* Lubricomp* JX00061 SABIC Innovative Plastics Europe PES
LNP* Lubricomp* JX91198 SABIC Innovative Plastics Europe PES
LNP* Lubricomp* JX91198 SABIC Innovative Plastics PES
LNP* Lubricomp* JZL012 SABIC Innovative Plastics Europe PES
LNP* Stat-Kon* JX89626 SABIC Innovative Plastics PES
LNP* Thermocomp* J1000ER SABIC Innovative Plastics Europe PES
LNP* Thermocomp* JF002 SABIC Innovative Plastics PES
LNP* Thermocomp* JF002 SABIC Innovative Plastics Asia Pacific PES
LNP* Thermocomp* JF002 SABIC Innovative Plastics Europe PES
LNP* Thermocomp* JF002R SABIC Innovative Plastics Europe PES
LNP* Thermocomp* JF003E SABIC Innovative Plastics PES
LNP* Thermocomp* JF003E SABIC Innovative Plastics Asia Pacific PES
LNP* Thermocomp* JF003L SABIC Innovative Plastics PES
LNP* Thermocomp* JF003XXZ SABIC Innovative Plastics PES
LNP* Thermocomp* JF003XXZ SABIC Innovative Plastics Asia Pacific PES
LNP* Thermocomp* JF004 SABIC Innovative Plastics PES
LNP* Thermocomp* JF004 SABIC Innovative Plastics Asia Pacific PES
LNP* Thermocomp* JF004 SABIC Innovative Plastics Europe PES
LNP* Thermocomp* JF004E SABIC Innovative Plastics PES
LNP* Thermocomp* JF004E SABIC Innovative Plastics Asia Pacific PES
LNP* Thermocomp* JF004E SABIC Innovative Plastics Europe PES
LNP* Thermocomp* JF004ER SABIC Innovative Plastics Europe PES
LNP* Thermocomp* JF004EXP SABIC Innovative Plastics PES
LNP* Thermocomp* JF004EXP SABIC Innovative Plastics Asia Pacific PES
LNP* Thermocomp* JF004L SABIC Innovative Plastics PES
LNP* Thermocomp* JF004P SABIC Innovative Plastics PES
LNP* Thermocomp* JF004P SABIC Innovative Plastics Asia Pacific PES
LNP* Thermocomp* JF004RXP SABIC Innovative Plastics Europe PES
LNP* Thermocomp* JF004Z SABIC Innovative Plastics Europe PES
LNP* Thermocomp* JF006 SABIC Innovative Plastics Europe PES
LNP* Thermocomp* JF006 SABIC Innovative Plastics PES
LNP* Thermocomp* JF006E SABIC Innovative Plastics PES
LNP* Thermocomp* JF006E SABIC Innovative Plastics Europe PES
LNP* Thermocomp* JF006EXZ SABIC Innovative Plastics PES
LNP* Thermocomp* JF006LXZ SABIC Innovative Plastics PES
LNP* Thermocomp* JF006LXZ SABIC Innovative Plastics Asia Pacific PES
LNP* Thermocomp* JF006LZZ SABIC Innovative Plastics PES
LNP* Thermocomp* JF008E SABIC Innovative Plastics PES
LNP* Thermocomp* JX97000 SABIC Innovative Plastics Europe PES
Lubriblend® PES GF30 TL15 TP Composites, Inc. PES
Luvocom® 1100/GF/20/EM/MR/BK Lehmann & Voss & Co. PES
Luvocom® 1100/GF/20/EM/MR Lehmann & Voss & Co. PES
Luvocom® 1100/GF/30/NAT Lehmann & Voss & Co. PES
Luvocom® 1100-7337/WT Lehmann & Voss & Co. PES
Luvocom® 1100-7721/WT9016 Lehmann & Voss & Co. PES
Luvocom® 1100-7725 VP Lehmann & Voss & Co. PES
Luvocom® 1100-7890 Lehmann & Voss & Co. PES
Luvocom® 1100-7939/GY Lehmann & Voss & Co. PES
Luvocom® 1100-8049 Lehmann & Voss & Co. PES
Luvocom® 1100-8134 Lehmann & Voss & Co. PES
Luvocom® 1100-8166 Lehmann & Voss & Co. PES
Luvocom® 1100-8194 Lehmann & Voss & Co. PES
Luvocom® 1100-8301 Lehmann & Voss & Co. PES
Luvocom® 1100-8325 Lehmann & Voss & Co. PES
Luvocom® 1100-8326 Lehmann & Voss & Co. PES
Luvocom® 1100-8401 Lehmann & Voss & Co. PES
NIMA NH OP66GF25 FR Ovation Polymers Inc. PES
OpteSTAT™ MB-SF 6000 Ovation Polymers Inc. PES
OpteSTAT™ NC PES 6010 Ovation Polymers Inc. PES
Radel® 5500 Westlake Plastics Company PES
Ratron® 250 Asia International Enterprise (Hong Kong) Limited PES
Ratron® 250C4 Asia International Enterprise (Hong Kong) Limited PES
Ratron® 250C6 Asia International Enterprise (Hong Kong) Limited PES
Ratron® 250C6-WR Asia International Enterprise (Hong Kong) Limited PES
Ratron® 250G4 Asia International Enterprise (Hong Kong) Limited PES
Ratron® 250G6 Asia International Enterprise (Hong Kong) Limited PES
Ratron® 250G6-WR Asia International Enterprise (Hong Kong) Limited PES
RTP Compounds 1400 A-100 RTP Company PES
RTP Compounds 1400 A-200 Z RTP Company PES
RTP Compounds 1400 A-300 RTP Company PES
RTP Compounds 1400 AG-210 RTP Company PES
RTP Compounds 1400 AG-220 RTP Company PES
RTP Compounds 1400 AG-230 RTP Company PES
RTP Compounds 1400 AG-320 RTP Company PES
RTP Compounds 1400 AG-330 RTP Company PES
RTP Compounds 1400 AG-360 M1 RTP Company PES
RTP Compounds 1400 AR 10 RTP Company PES
RTP Compounds 1400 AR 15 RTP Company PES
RTP Compounds 1400 AR 5 RTP Company PES
RTP Compounds 1400 GB 20 RTP Company PES
RTP Compounds 1400 GB 30 RTP Company PES
RTP Compounds 1400 L RTP Company PES
RTP Compounds 1400 N L RTP Company PES
RTP Compounds 1400 N RTP Company PES
RTP Compounds 1400 R-4300 UV RTP Company PC+PES
RTP Compounds 1400 TFE 10 RTP Company PES
RTP Compounds 1400 TFE 15 SI 2 RTP Company PES
RTP Compounds 1400 TFE 15 RTP Company PES
RTP Compounds 1400.5 L MG 15 RTP Company PES
RTP Compounds 1400.5 N RTP Company PES
RTP Compounds 1400 RTP Company PES
RTP Compounds 1401 B L RTP Company PES
RTP Compounds 1401 L RTP Company PES
RTP Compounds 1401 N RTP Company PES
RTP Compounds 1401 RTP Company PES
RTP Compounds 1401N L RTP Company PES
RTP Compounds 1402 L RTP Company PES
RTP Compounds 1402 N L RTP Company PES
RTP Compounds 1402 N Z RTP Company PES
RTP Compounds 1402 N RTP Company PES
RTP Compounds 1402 RTP Company PES
RTP Compounds 1403 B RTP Company PES
RTP Compounds 1403 L RTP Company PES
RTP Compounds 1403 N L RTP Company PES
RTP Compounds 1403 N Z RTP Company PES
RTP Compounds 1403 N RTP Company PES
RTP Compounds 1403 TFE 10 RTP Company PES
RTP Compounds 1403 TFE 15 RTP Company PES
RTP Compounds 1403 RTP Company PES
RTP Compounds 1404 N L RTP Company PES
RTP Compounds 1405 B RTP Company PES
RTP Compounds 1405 HF TFE 15 RTP Company PES
RTP Compounds 1405 HF TFE 5 RTP Company PES
RTP Compounds 1405 L RTP Company PES
RTP Compounds 1405 N L RTP Company PES
RTP Compounds 1405 N RTP Company PES
RTP Compounds 1405 TFE 15 RTP Company PES
RTP Compounds 1405 Z RTP Company PES
RTP Compounds 1405 RTP Company PES
RTP Compounds 1407 N RTP Company PES
RTP Compounds 1407 Z RTP Company PES
RTP Compounds 1407 RTP Company PES
RTP Compounds 1475 L RTP Company PES
RTP Compounds 1475 N RTP Company PES
RTP Compounds 1475 RTP Company PES
RTP Compounds 1481 N TFE 15 RTP Company PES
RTP Compounds 1481 N RTP Company PES
RTP Compounds 1481 TFE 10 RTP Company PES
RTP Compounds 1481 RTP Company PES
RTP Compounds 1482 AR 10 RTP Company PES
RTP Compounds 1482 HEC RTP Company PES
RTP Compounds 1482 N TFE 15 RTP Company PES
RTP Compounds 1482 N RTP Company PES
RTP Compounds 1482 RTP Company PES
RTP Compounds 1483 B TFE 10 RTP Company PES
RTP Compounds 1483 HEC RTP Company PES
RTP Compounds 1483 N RTP Company PES
RTP Compounds 1483 TFE 10 RTP Company PES
RTP Compounds 1483 RTP Company PES
RTP Compounds 1485 N RTP Company PES
RTP Compounds 1485 TFE 15 RTP Company PES
RTP Compounds 1485 RTP Company PES
RTP Compounds 1487 N RTP Company PES
RTP Compounds 1487 RTP Company PES
RTP Compounds 1499 X 92453 RTP Company PES
RTP Compounds EMI 1461 RTP Company PES
RTP Compounds ESD A 1480 N RTP Company PES
RTP Compounds ESD A 1480 RTP Company PES
RTP Compounds ESD C 1480 N RTP Company PES
RTP Compounds ESD C 1480 RTP Company PES
RTP Compounds ESD C 1680 RTP Company PES
SUMIKAEXCEL® PES 3600G Sumitomo Chemical Co., Ltd. PES
SUMIKAEXCEL® PES 3601GL20 Sumitomo Chemical Co., Ltd. PES
SUMIKAEXCEL® PES 3601GL30 Sumitomo Chemical Co., Ltd. PES
SUMIKAEXCEL® PES 4100G Sumitomo Chemical Co., Ltd. PES
SUMIKAEXCEL® PES 4101GL20 Sumitomo Chemical Co., Ltd. PES
SUMIKAEXCEL® PES 4101GL30 Sumitomo Chemical Co., Ltd. PES
SUMIKAEXCEL® PES 4800G Sumitomo Chemical Co., Ltd. PES
SUMIPLOY® AS1411 Sumitomo Chemical Co., Ltd. PES
SUMIPLOY® E3010 Sumitomo Chemical Co., Ltd. PES
SUMIPLOY® FS2200 Sumitomo Chemical Co., Ltd. PES
SUMIPLOY® GS5420 Sumitomo Chemical Co., Ltd. PES
SUMIPLOY® MS5620 Sumitomo Chemical Co., Ltd. PES
SUMIPLOY® PS5660 Sumitomo Chemical Co., Ltd. PES
TRIBOCOMP® PES CF10 TS10 EPIC Polymers Ltd. PES
TRIBOCOMP® PES CF30 TS0 EPIC Polymers Ltd. PES
TRIBOCOMP® PES GF30 TS0 EPIC Polymers Ltd. PES
TRIBOCOMP® PES TS0 EPIC Polymers Ltd. PES
Ultrason® E 1010 NAT BASF Corporation PES
Ultrason® E 1010 BASF Corporation PES
Ultrason® E 2010 C6 BASF Corporation PES
Ultrason® E 2010 G4 BASF Corporation PES
Ultrason® E 2010 G6 SW 15038 BASF Corporation PES
Ultrason® E 2010 G6 UN BASF Corporation PES
Ultrason® E 2010 G6 BASF Corporation PES
Ultrason® E 2010 MR GR 30359 BASF Corporation PES
Ultrason® E 2010 MR HP BASF Corporation PES
Ultrason® E 2010 NAT BASF Corporation PES
Ultrason® E 2010 SW Q31 10088 BASF Corporation PES
Ultrason® E 2010 UN Q26 BASF Corporation PES
Ultrason® E 2010 BASF Corporation PES
Ultrason® E 2020 P (EU) BASF Corporation PES
Ultrason® E 2020 P SR BASF Corporation PES
Ultrason® E 2020 P BASF Corporation PES
Ultrason® E 3010 MR UN BASF Corporation PES
Ultrason® E 3010 NAT BASF Corporation PES
Ultrason® E 3010 BASF Corporation PES
Ultrason® E 6020 P (EU) BASF Corporation PES
Ultrason® E 6020 P BASF Corporation PES
Ultrason® E KR 4113 BASF Corporation PES
UTTAP SF 50020 GF Ovation Polymers Inc. PES
UTTAP SF 50030 GF Ovation Polymers Inc. PES
UTTAP SF 600 Ovation Polymers Inc. PES
Veradel® 3000P Solvay Specialty Polymers PES
Veradel® 3000RP Solvay Specialty Polymers PES
Veradel® 3100P Solvay Specialty Polymers PES
Veradel® 3200 Solvay Specialty Polymers PES
Veradel® 3200P Solvay Specialty Polymers PES
Veradel® 3250 Solvay Specialty Polymers PES
Veradel® 3300 PREM Solvay Specialty Polymers PES
Veradel® 3320GF Solvay Specialty Polymers PES
Veradel® 3330GF Solvay Specialty Polymers PES
Veradel® 3400 Solvay Specialty Polymers PES
Veradel® 3400P Solvay Specialty Polymers PES
Veradel® 3500 Solvay Specialty Polymers PES
Veradel® 3600 Solvay Specialty Polymers PES
Veradel® 3600P Solvay Specialty Polymers PES
Veradel® 3600RP Solvay Specialty Polymers PES
Veradel® A-201 Solvay Specialty Polymers PES
Veradel® A-301 Solvay Specialty Polymers PES
Veradel® A-304P Solvay Specialty Polymers PES
Veradel® A-702 Solvay Specialty Polymers PES
Veradel® A-704P Solvay Specialty Polymers PES
Veradel® AG-320 Solvay Specialty Polymers PES
Veradel® AG-330 Solvay Specialty Polymers PES
Virantage® VW-10200 RP, RFP, RSFP Solvay Specialty Polymers PES
Virantage® VW-10300 P, FP Solvay Specialty Polymers PES
Virantage® VW-10700 RP, RFP, RSFP Solvay Specialty Polymers PES
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